Evaluation of heavy metals contamination, lead and manganese in the around soils of Yasouj Cement Factory

Document Type : Research Paper

Authors

1 null

2 Yasouj University

Abstract

Atmospheric emissions from cement industry are one of the major sources of environmental pollution. Heavy metals are among the most relevant substances emitted during the process of cement manufacture. The purpose of this study was to investigate the contamination of heavy metals of lead and manganese in the lands around the Yasouj Cement Factory. Sixty one soil samples of land around the factory were sampled at depths of 0-30 cm. Some soil properties such as total concentration of lead, manganese, acidity (pH), electrical conductivity (EC), organic matter and calcium carbonate equivalent were measured. To verify the normality of the data the Kolmogorov-Smirnov test was used. In the normal data series, Kriging method was used to prepare zoning maps. In an abnormal data series, the IDW method was used to prepare zoning maps. PH values ranged from 3.72 to 8.02, the electrical conductivity ranged from 0.07 to 0.96, the organic matter ranged from 0.82 to 2.19 and calcium carbonate equivalent ranged from 18.44 to 54 percent. Lead concentrations in soil samples varied from 2.25 to 168.75 mg kg-1 and manganese values ranged from 45 to 708 mg kg-1. The results of zoning in the study area showed that the highest amount of lead and manganese are inside the factory. The levels of lead and manganese in a number of samples harvested within the factory were higher than the global standard of USEPA, that indicating the accumulation of these metals in the soil and contamination of this factory. From these findings, it is highly recommended that environmental auditing of the cement production line be carried out to reduce the release of pollutants. It is also important that remediation activities be carried out on the soil to reduce the levels of lead and manganese to avert potential ecological disasters.

Keywords

Abimbola, A., Kehinde-Phillips, O., Olatunji, A., 2007. The Sagamu cement factory, SW Nigeria: Is the dust generated a potential health hazard? Environmental Geochemistry and Health 29, 163-167.
Addo, M.A., Darko, E.O., Gordon, C., Nyarko, B.J.B., Gbadago, J.K., Nyarko, E., Affum, H.A., Botwe, B.O., 2012. Evaluation of heavy metals contamination of soil and vegetation in the vicinity of a cement factory in the Volta region, Ghana. International Journal of Environmental Science and Technology 2, 40–50.
Adekola, F.A., Inyinbor, A.A., Abdul Raheem, A.M.O., 2012. Heavy metals distribution and speciation in soils around a Mega Cement Factory in NorthCentral Nigeria. Ethiopian Journal of Environmental Studies and Management 5(1), 11–19.
Adrino, D.C., 2001. Trace element in terrestrial environment, biogeochemistry, bioavailability and risk of metal. Springer-Verlag, New York, 867p.
Al-Khashman, O.A., Shawabkeh, A.R., 2006. Metals distribution in soils around the cement factory in southern Jordan.  Environmental Pollution 140, 387-394.
Al-Omran, A.M., El-Maghraby, S.E., Nadeem, M.E.A., El-Eter, A.M., AlQahtani, S.M.I., 2011. Impact of cement dust on some soil properties around the cement factory in Al-Hasa Oasis, Saudi Arabia. American-Eurasian journal of agricultural and environmental sciences 11(6), 840-846.
Alwadi, A.R., 1999. Manual of oceanographic observation and pollutant analysis method. (MOOPAM), 261p.
Ameh, E.G., Kolawole, M.S., Imeokparia, E.G., 2011. Using Factor-Cluster analysis and Enrichment methods to evaluate impact of cement production on stream sediments around Obajana cement factory in kogi state, North Central Nigeria. Pelagia Research Library 76-89.
Amini, M., Afyoni, M., Khademi, H., 2006. Modeling of mass balance of Cd and Pb in agricultural lands of Isfahan region.  Journal of Agricultural Science and Technology 10(4), 77-89. (In Persian)
 Baby, S., Singh, N.A., Shrivastava, P., Nath, S.R., Kumar, S.S., Singh, D., Vivek, K., 2008. Impact of dust emission on plant vegetation of vicinity of cement plant. Environmental Engineering and Management Journal 7(1), 31-35.
 Ebqa’ai, M., Ibrahim, B., 2017. Application of multivariate statistical analysis in the pollution and health risk of traffic related heavy metals. Environmental Geochemistry and Health 39, 1441-1456.
 Guo, G., Wu, F., Xie, F., Zhang, R., 2012. Spatial distribution and pollution assessment of  heavy metals in urban soils from southwest China. Journal of Environmental Sciences 24, 410–418.
 Gupta, P.K., 2000. Soil, plant, water and fertilizer analysis. Agrobios, New Delhi, India, 438 p.
 Hernandez, L., Probst, A., Probst, J.L., Ulrich, E., 2003. Heavy metal distribution in some French forest soil: evidence for atmospheric contamination. Science of the Total Environment 312, 195-219.
 Kabata-Pendias, A., and Pendias, H., 1992. Trace element in soils and plants. Boca Raton: CRC Press, 548 p.
 Karimi Nezhad, M.T., Tabatabaii, S.M., & Gholami, A., 2015. Geochemical assessment of steel smelter-impacted urban soils, Ahvaz, Iran. Journal of Geochemical Exploration 152, 91-109.
 Lafta, J.G., Fadhil, H.S., Hussein A.A., 2013. Heavy metals distribution and the variation of soil properties around Alqaim cement factory in Anbar Governorate – Iraq. International Journal of Advanced Engineering and Technology (IJAET) 3(1), 289-291.
 Loeppert, R.H., Sparks, D.L., 1996. Carbonate and gypsum. In: Sparks, D.L. (Ed.). Methods of soil analysis. Part 3: Chemical properties. Soil Science Society of America, Madison, Wisconsin. pp. 437–474.
 Mahmoudi, S., Mohammadi, J., Naderi, M., 2013. Statistical and spatial distribution of some heavy metals in surface soil particle size fractions in South of Isfahan. Journal of Water Soil Conservation (JSWC) 20(2), 1-22. (in Persian)
 Mandal, A., Voutchkov, M., 2011. Heavy metals in soils around the cement factory in Rockfort, Kingston, Jamaica. Geosciences 2, 48–54.
 Moslempour, M.E., Shahdadi, S., 2013. Assessment of heavy metal contamination in soils around of Khash Cement Plant, SE Iran. Iranian Journal of Earth Sciences (IJES) 5,111–118.
 Nelson, D.W., Sommers, L.E., 1996. Total carbon, organic carbon and organic matter. In: Sparks, D.L. (Ed.). Methods of soil analysis. Part 3: Chemical properties. Soil Science Society of America, Madison. Wisconsin. pp. 961–1010.
 Ogunbileje, J.O., Sadagoparamanujam, V.M., Anetor, J.I., Farombi, E.O., Akinosun, O.M., Okorodudu, A.O., 2013. Lead, mercury, cadmium, chromium, nickel, copper, zinc, calcium, iron, manganese and chromium (VI) levels in Nigeria and United States of America cement dust. Chemosphere 90(11), 2743-2749.
 Ogunkunle, C.O., 2014. Contamination and spatial distribution of heavy metals in top soil surrounding a mega cement factory. Atmospheric Pollution Research (APR) 5(2), 270-282.
Pourkhabbaz, H.R., Javanmardi, S., Yusefnia, H., Eslami, M., Makrouni, S., Aghdar, H., 2016. Environmental evaluation of heavy metals contamination in soils around the Cement Factory in Behbahan city. Journal of Geography and Environmental Planning (JGEP) 27(3), 87-106.
Qishlaqi, A., Moore, F., Forghani, G., 2009. Characterization of metal pollution in soils under two landuse patterns in the Angouran region, NW Iran; a study based on multivariate data analysis. Journal of Hazardous Materials 172, 374–384.
Sayadi, M.H., Rezaei, M.R., Hajiani, M., 2018. Investigation of surface soil contaminationby lead and chromium around the Qayen cement factory. Journal of Environment and Water Engineering 3(4), 312 – 322.
 Schuhmacher, M., Bocio, A., Agramunt, M.C., Domingo, J.L., de Kok, H.A., 2002. PCDD/F and metal concentrations in soil and herbage samples collected in the vicinity of a cement plant. Chemosphere 48(2), 209-217.
 Sielaff, K., Einax, J.W., 2007. The application of multivariate statistical methods for the evaluation of soil profiles. Journal of Soils and Sediments (JSS) 7(1), 45–52.
 Zhong, T., Xue, D., Zhao, L., Zhang, X., 2018. Concentration of heavy metals in vegetables and potential health risk assessment in China. Environ Geochem Health 40(1), 313-322.